Direct functionalization of arenes by primary alcohol sulfonate esters catalyzed by gold(III).
نویسندگان
چکیده
Alkylation of arenes by primary alcohol triflate or methanesulfonate esters can be efficiently catalyzed by AuCl3 with silver triflate.
منابع مشابه
Efficient functionalization of aromatic C-H bonds catalyzed by gold(III) under mild and solvent-free conditions.
A gold(III)-catalyzed carbon-carbon bond formation reaction between arenes and electron-deficient alkynes or alkenes is described. Electron-rich arenes can be efficiently functionalized with the alkyne or alkene substrates. This reaction can be run with neat reactants at ambient temperature. Under the "solventless" conditions, clean product was obtained from a reaction of equal molar amounts of...
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عنوان ژورنال:
- Journal of the American Chemical Society
دوره 126 42 شماره
صفحات -
تاریخ انتشار 2004